Dégradation de micro-polluants organiques par des procédés biologiques innovants (thèse: 2014 - 2017)
-en- Activités
Traitement des eaux
Micro-polluants
Bio-réacteur à
membrane
Biodégradation
-en- Publications scientifiques au M2P2
2020
Camille Grandclement, Anne Piram, Marie-Eleonore Petit, Isabelle Seyssiecq, Isabelle Laffont-Schwob, et al.. Biological Removal and Fate Assessment of Diclofenac Using Bacillus subtilis and Brevibacillus laterosporus Strains and Ecotoxicological Effects of Diclofenac and 49-Hydroxy-diclofenac. Journal of Chemistry , 2020, 2020, pp.9789420. ⟨10.1155/2020/9789420⟩. ⟨hal-02564026⟩ Plus de détails...
Since bacterial consortia involved in conventional wastewater treatment processes are not efficient in removing diclofenac (DCF), an emerging pollutant frequently detected in water bodies, the identification of microorganisms able to metabolise this pharmaceutical compound is relevant. us, DCF removal was investigated using bacteria isolated from aqueous stock solutions of this micro-pollutant and identified as Bacillus and Brevibacillus species using 16S rRNA gene sequencing. A 100% DCF removal was achieved after 17 hours of experiment at 20°C in a nutrient medium; the biodegradation kinetic followed a pseudo-first order (k biol = 11 L·g SS −1 ·d −1). Quantitative assessment of DCF removal showed that its main route was biotic degradation. e main degradation product of DCF, 4′-hydroxy-diclofenac (4′-OH-DCF), was identified using liquid chromatography-electrospray ionisation high-resolution mass spectrometry. Since the ecotoxicological impact of 4′-hydroxy-diclofenac was not reported in the literature, the ecotoxicity of DCF and its metabolite were tentatively evaluated using Vibrio fischeri bioassays. Results from these tests showed that this metabolite is not more toxic than its parent compound and may hopefully be an intermediate product in the DCF transformation. Indeed, no significant difference in ecotoxicity was observed after 30 min between DCF (50 should be writtten in subscript all along the manuscript in EC 50 = 23 ± 4 mg·L −1) and 4′-hydroxy-diclofenac (EC 50 = 19 ± 2 mg·L −1). Besides, the study highlighted a limit of the Microtox ® bioassay, which is largely used to assess ecotoxicity. e bioluminescence of Vibrio fischeri was impacted due to the production of microbial activity and the occurrence of some carbon source in the studied medium.
Camille Grandclement, Anne Piram, Marie-Eleonore Petit, Isabelle Seyssiecq, Isabelle Laffont-Schwob, et al.. Biological Removal and Fate Assessment of Diclofenac Using Bacillus subtilis and Brevibacillus laterosporus Strains and Ecotoxicological Effects of Diclofenac and 49-Hydroxy-diclofenac. Journal of Chemistry , 2020, 2020, pp.9789420. ⟨10.1155/2020/9789420⟩. ⟨hal-02564026⟩
Camille Grandclement, Isabelle Seyssiecq, Anne Piram, Pascal Wong-Wah-Chung, Guillaume Vanot, et al.. From the conventional biological wastewater treatment to hybrid processes, the evaluation of organic micropollutant removal: A review. Water Research, 2017, 111, pp.297-317. ⟨10.1016/j.watres.2017.01.005⟩. ⟨hal-01456484⟩ Plus de détails...
Because of the recalcitrance of some micropollutants to conventional wastewater treatment systems, the occurrence of organic micropollutants in water has become a worldwide issue, and an increasing environmental concern. Their biodegradation during wastewater treatments could be an interesting and low cost alternative to conventional physical and chemical processes. This paper provides a review of the organic micropollutants removal efficiency from wastewaters. It analyses different biological processes, from conventional ones, to new hybrid ones. Micropollutant removals appear to be compound-and process-dependent, for all investigated processes. The influence of the main physico-chemical parameters is discussed, as well as the removal efficiency of different microorganisms such as bacteria or white rot fungi, and the role of their specific enzymes. Even though some hybrid processes show promising micropollutant removals, further studies are needed to optimize these water treatment processes, in particular in terms of technical and economical competitiveness.
Camille Grandclement, Isabelle Seyssiecq, Anne Piram, Pascal Wong-Wah-Chung, Guillaume Vanot, et al.. From the conventional biological wastewater treatment to hybrid processes, the evaluation of organic micropollutant removal: A review. Water Research, 2017, 111, pp.297-317. ⟨10.1016/j.watres.2017.01.005⟩. ⟨hal-01456484⟩
X. Litaudon, S. Abduallev, M. Abhangi, P. Abreu, M. Afzal, et al.. Overview of the JET results in support to ITER. Nuclear Fusion, 2017, 57 (10), pp.102001. ⟨10.1088/1741-4326/aa5e28⟩. ⟨hal-01660974⟩ Plus de détails...
The 2014-2016 JET results are reviewed in the light of their significance for optimising the ITER research plan for the active and non-active operation. More than 60 h of plasma operation with ITER first wall materials successfully took place since its installation in 2011. New multi-machine scaling of the type I-ELM divertor energy flux density to ITER is supported by first principle modelling. ITER relevant disruption experiments and first principle modelling are reported with a set of three disruption mitigation valves mimicking the ITER setup. Insights of the L-H power threshold in Deuterium and Hydrogen are given, stressing the importance of the magnetic configurations and the recent measurements of fine-scale structures in the edge radial electric. Dimensionless scans of the core and pedestal confinement provide new information to elucidate the importance of the first wall material on the fusion performance. H-mode plasmas at ITER triangularity (H = 1 at beta(N) similar to 1.8 and n/n(GW) similar to 0.6) have been sustained at 2 MA during 5 s. The ITER neutronics codes have been validated on high performance experiments. Prospects for the coming D-T campaign and 14 MeV neutron calibration strategy are reviewed.
X. Litaudon, S. Abduallev, M. Abhangi, P. Abreu, M. Afzal, et al.. Overview of the JET results in support to ITER. Nuclear Fusion, 2017, 57 (10), pp.102001. ⟨10.1088/1741-4326/aa5e28⟩. ⟨hal-01660974⟩
O. Kazakov, J. Ongena, E. Lerche, M. Mantsinen, D. Van eester, et al.. Efficient generation of energetic ions in multi-ion plasmas by radio-frequency heating. Nature Physics, 2017, 13 (10), pp.973-978. ⟨10.1038/NPHYS4167⟩. ⟨cea-01898634⟩ Plus de détails...
We describe a new technique for the efficient generation of high-energy ions with electromagnetic ion cyclotron waves in multi-ion plasmas. The discussed ‘three-ion’ scenarios are especially suited for strong wave absorption by a very low number of resonant ions. To observe this effect, the plasma composition has to be properly adjusted, as prescribed by theory. We demonstrate the potential of the method on the world-largest plasma magnetic confinement device, JET (Joint European Torus, Culham, UK), and the high-magnetic-field tokamak Alcator C-Mod (Cambridge, USA). The obtained results demonstrate efficient acceleration of $^3$He ions to high energies in dedicated hydrogen–deuterium mixtures. Simultaneously, effective plasma heating is observed, as a result of the slowing-down of the fast $^3$He ions. The developed technique is not only limited to laboratory plasmas, but can also be applied to explain observations of energetic ions in space-plasma environments, in particular, $^3$He-rich solar flares.
O. Kazakov, J. Ongena, E. Lerche, M. Mantsinen, D. Van eester, et al.. Efficient generation of energetic ions in multi-ion plasmas by radio-frequency heating. Nature Physics, 2017, 13 (10), pp.973-978. ⟨10.1038/NPHYS4167⟩. ⟨cea-01898634⟩
Eric Serre, Sandrine Hugues, Emilia Crespo del Arco, Anthony Randriamampianina, Patrick Bontoux. Axisymmetric and three-dimensional instabilities in an Ekman boundary layer flow. International Journal of Heat and Fluid Flow, 2001, 22 (1), pp.82-93. ⟨hal-01023080⟩ Plus de détails...
Eric Serre, Sandrine Hugues, Emilia Crespo del Arco, Anthony Randriamampianina, Patrick Bontoux. Axisymmetric and three-dimensional instabilities in an Ekman boundary layer flow. International Journal of Heat and Fluid Flow, 2001, 22 (1), pp.82-93. ⟨hal-01023080⟩
Journal: International Journal of Heat and Fluid Flow
